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Chapter 3: Builders and water softeners · Part 2: Phosphonates

DTPMP

  • Made from a hazardous chemical
Also called
diethylenetriamine penta(methylene phosphonic acid), phosphonate
Found in
laundry powder with bleach

The worst fact: a 2025 lab study in Nature Communications showed it can turn into glyphosate, the weedkiller, when it reacts with manganese minerals or dissolved manganese, including in wastewater. Up to 0.42% of it became glyphosate (and up to 27% became AMPA). How much this happens in real rivers isn't known.

Why brands use it: it keeps bleach stable and stops scale in laundry powder.

Take care if: you get it in your eyes. Most company reports class it as causing serious eye damage.

Comes from: phosphorous acid, an amine and formaldehyde. Australia classes formaldehyde as "May cause cancer". That doesn't mean it's in the product, but it's not a great starting point for something you clean with.

Myth check: nil.

Contaminants: nil.

Fair to say: the industry's risk assessment concluded that, despite some conflicting data, the weight of evidence suggests it isn't mutagenic.

Correct as of November 2026. What the badges mean

Sources

  • Safe Work Australia. Hazardous Chemical Information System (HCIS): classifications for each chemical, and for formaldehyde.
  • HERA. Risk assessments: STPP (2003) and STPP eutrophication note (2003); phosphonates (2004); zeolite A (2004); soluble silicates (2005); polycarboxylates parts I and II (2014).
  • Röhnelt et al. Glyphosate formation from aminopolyphosphonates. Nat Commun 2025.

The full source list is at the end of Chapter 3.